Chemistry 5th edition

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John McMurry and Robert C. Fay
Publisher: Pearson Education


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  • Chapter 1: Chemistry: Matter and Measurement
    • 1: Key Concept Problems (6)
    • 1.1: Approaching Chemistry: Experimentation
    • 1.2-4: Elements and the Periodic Table (15)
    • 1.5-12: Units and Significatn Figures (16)
    • 1.13: Unit Conversions (7)
    • 1.8: Temperature (6)
    • 1.10: Density (5)
    • 1: Chapter Problems (14)
    • WebAssign Answer Entry Tutorials (1)

  • Chapter 2: Atoms, Molecules, and Ions
    • 2: Key Concept Problems (5)
    • 2.1: Conservation of Mass and the Law of Definite Proportions
    • 2.2-6: Atomic Theory (9)
    • 2.3-6: Elements and Atoms (16)
    • 2.7-8: Compounds and Mixtures, Molecules and Ions (16)
    • 2.9: Acids and Bases (3)
    • 2.10: Naming Compounds (6)
    • 2: Chapter Problems (16)
    • WebAssign Answer Entry Tutorials (1)

  • Chapter 3: Formulas, Equations and Moles
    • 3: Key Concept Problems (5)
    • 3.1: Balancing Chemical Equations (2)
    • 3.2: Chemical Symbols on Different Levels
    • 3.3-4: Molecular Masses and Moles (6)
    • 3.4: Stoichiometry: Chemical Arithmetic (3)
    • 3.5-6: Limiting Reactants and Reaction Yield (2)
    • 3.7-10: Molarity, Solution Stoichiometry, Dilution, and Titration (4)
    • 3.11-12: Formulas and Elemental Analysis (3)
    • 3: Chapter Problems (2)
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  • Chapter 4: Reactions in Aqueous Solution
    • 4: Key Concept Problems (6)
    • 4.1: Some Ways That Chemical Reactions Occur
    • 4.2: Electrolytes in Aqueous Solution
    • 4.3: Aqueous Reactions and net Ionic Equations (2)
    • 4.4: Precipitation Reactions and Solubility Guidelines (1)
    • 4.5: Acids, Bases, and Neutralization Reactions (1)
    • 4.6-7: Redox Reactions and Oxidation Numbers (4)
    • 4.8: The Activity Series of the Elements
    • 4.9-10: Balancing Redox Reactions (3)
    • 4.11: Redox Tritations [84-91 (4)
    • 4.12: Some Applications of Redox Reactions
    • 4: Chapter Problems
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  • Chapter 5: Periodicity and Atomic Structure
    • 5: Key Concept Problems (5)
    • 5.1: Development of the Periodic Table
    • 5.2: Electromagnetic Energy (3)
    • 5.3: Atomic Spectra (1)
    • 5.4: Particlelike Properties of Electromagnetic Energy
    • 5.5: Wavelike Properties of Matter
    • 5.6: Quantum Mechanics and the Heisenberg Uncertainty Principle
    • 5.7-8: Orbitals and Quantum Numbers (3)
    • 5.8: The Shapes of Orbitals
    • 5.9: Quantum Mechanics and Atomic Line Spectra
    • 5.10: Electron Spin and the Pauli Exclusion Principle
    • 5.11-13: Electron Configurations (4)
    • 5.14: Electron Configurations and the Periodic Table
    • 5.15: Electron Configurations and Periodic Properties: Atomic Radii (1)
    • 5: Chapter Problems
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  • Chapter 6: Ionic Bonds and Some Main-Group Chemistry
    • 6: Key Concept Problems (3)
    • 6.1-5: Ions, ionization Energy, and Electron Affinity (4)
    • 6.2: Ionic Radii
    • 6.3: Ionization Energy
    • 6.4: Higher Ionization Energies
    • 6.5: Electron Affinity
    • 6.6-7: Lattice Energy and Ionic Bonds (3)
    • 6.8: The Octet Rule
    • 6.9-13: Main-Group Chemistry (1)
    • 6: Chapter Problems
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  • Chapter 7: Covalent Bonds and Molecular Structure
    • 7: Key Concept Problems (1)
    • 7.1: The Covalent Bond
    • 7.2: Strengths of Covalent Bonds
    • 7.3: A Comparison of Ionic and Covalent Compounds
    • 7.4: Electronegativity and Polar Covalent Bonds (2)
    • 7.5-7: Electron-Dot Structures and Resonance (10)
    • 7.8: Formal Charges (6)
    • 7.9: The VSEPR Model (4)
    • 7.10: Valence Bond Theory
    • 7.11-15: Hybrid Orbitals and Molecular Orbital Theory (3)
    • 7: Chapter Problems (11)
    • WebAssign Answer Entry Tutorials (2)

  • Chapter 8: Thermochemistry: Chemical Energy
    • 8: Key Concept Problems (3)
    • 8.1-4: Heat, Work, and Energy (2)
    • 8.5-7: Energy and Enthalpy (4)
    • 8.8: Calorimetry and Heat Capacity (3)
    • 8.9-10: Hess's Law and heats of Formation (2)
    • 8.11: Bond Dissociation Energies (1)
    • 8.12: Fossil Fuels, Fuel Efficiency, and Heats of Combustion
    • 8.13-14: Free Energy and Entropy (4)
    • 8: Chapter Problems (1)
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  • Chapter 9: Gases: Their Properties and Behavior
    • 9: Key Concept Problems (3)
    • 9.1: Gases and Gas Pressure (1)
    • 9.2-3: The Gas Laws (4)
    • 9.4: Gas Stoichiometry (3)
    • 9.5: Dalton's Law and Mole Fraction (1)
    • 9.6-7: Kinetic-Molecular Theory and Graham's Law (2)
    • 9: Chapter Problems (1)
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  • Chapter 10: Liquids, Solids, and Phase Changes
    • 10: Key Concept Problems (5)
    • 10.1-2: Dipole Moments and Intermolecular Forces (2)
    • 10.3: Some Properties of Liquids
    • 10.4-5: Vapor Pressure and Phase Changes 44-67] (4)
    • 10.6: Kinds of Solids
    • 10.7: Probing the Structure of Solids: X-Ray Crystallography
    • 10.8-9: Structures of Solids (2)
    • 10.10: Structures of Some Covalent Network Solids
    • 10.11: Phase Diagrams (1)
    • 10: Chapter Problems (2)
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  • Chapter 11: Solutions and Their Properties
    • 11: Key Concept Problems (3)
    • 11.1: Solutions
    • 11.2: Solutions and Energy Changes (4)
    • 11.3: Units of Concentration (11)
    • 11.4: Solubility and Henry's Law (2)
    • 11.5-8: Colligative Properties [76-99 (10)
    • 11.9: Uses of Colligative Properties (3)
    • 11: Chapter Problems (6)
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  • Chapter 12: Chemical Kinetics
    • 12: Key Concept Problems (6)
    • 12.1: Reaction Rates (3)
    • 12.2-3: Rate Laws (3)
    • 12.4-7: Integrated Rate Law; Half-Life (10)
    • 12.8-10: Reaction Mechanisms (6)
    • 12.11-12: The Arrhenius Equation (3)
    • 12.13-14: Catalysis (4)
    • 12: Chapter Problems (7)
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  • Chapter 13: Chemical Equilibrium
    • 13: Key Concept Problems (3)
    • 13.1-4: Equilibrium Expressions and Equilibrium Constants (10)
    • 13.5: Using the Equilibrium Constant (10)
    • 13.6-10: Le Chatelier's Principle (6)
    • 13.11: Chemical Equilibrium and Chemical Kinetics (2)
    • 13: Chapter Problems (9)
    • WebAssign Answer Entry Tutorials

  • Chapter 14: Aqueous Equilibria: Acids and Bases
    • 14: Key Concept Problems (6)
    • 14.1-2: Acid-Base Concepts (5)
    • 14.3: Hydrated Protons and Hydronium Ions
    • 14.4-5: Dissociation of Water; pH (5)
    • 14.6: Measuring pH
    • 14.7: Strong Acids and Strong Bases (2)
    • 14.8-10: Weak Acids (2)
    • 14.9: Calculating Equilibrium Concentrations in Solutions of Weak Acids
    • 14.10: Percent Dissociation in Solutions of Weak Acids
    • 14.11: Polyprotic Acids (1)
    • 14.12-13: Weak Bases; Relation between Ka and Kb (3)
    • 14.14: Acid-Base Properties of Salts (3)
    • 14.15: Factors That Affect Acid Strength (2)
    • 14.16: Lewis Acids and Bases (1)
    • 14: Chapter Problems (2)
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  • Chapter 15: Applications of Aqueous Equilibria
    • 15: Key Concept Problems (5)
    • 15.1: Neutralization Reactions (1)
    • 15.2: The Common-Ion Effect (4)
    • 15.3-4: Buffer Solutions (5)
    • 15.5-9: pH titration Curves (4)
    • 15.10-11: Solubility Equilibria (3)
    • 15.12: Factors That Affect Solubility (3)
    • 15.13-15: Precipitation; Qualitative Analysis (1)
    • 15: Chapter Problems (3)
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  • Chapter 16: Thermodynamics: Entropy, Free Energy, and Equilibrium
    • 16: Key Concept Problems (2)
    • 16.1: Spontaneous Processes (3)
    • 16.2-4: Entropy (6)
    • 16.5: Standard Molar Entroopies and Standard Entropies of Reaction (2)
    • 16.6: Entropy and the Second Law of Thermodynamics (4)
    • 16.7: Free Energy (4)
    • 16.8-9: Stamdard Free-Energy Changes and Standard Free Energies of Formation (7)
    • 16.10-11: Free Energy, Composition, and Chemical Equilibrium (6)
    • 16: Chapter Problems (13)
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  • Chapter 17: Electrochemistry
    • 17: Key Concept Problems (6)
    • 17.1-2: Galvanic Cells (3)
    • 17.3-5: Cell Potentials and Free-Energy Changes; Standard Reduction Potentials (9)
    • 17.6-7: The Nernst Equation (5)
    • 17.8: Standard Cell Potentials and Equilibrium Constants (4)
    • 17.9-11: Batteries; Fuel Cells; Corrosion (5)
    • 17.12-14: Electrolysis (4)
    • 17: Chapter Problems (5)
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  • Chapter 18: Hydrogen, Oxygen, and Water
    • 18: Key Concept Problems (7)
    • 18.1-5: Chemistry of Hydrogen (7)
    • 18.6-12: Chemistry of Oxygen (7)
    • 18.13-15: Chemistry of Water (4)
    • 18: Chapter Problems (5)
    • WebAssign Answer Entry Tutorials

  • Chapter 19: The Main-Group Elements
    • 19: Key Concept Problems (2)
    • 19.1-2: General properties and Periodic Trends (12)
    • 19.3-4: The Group 3A Elements (3)
    • 19.5-8: The Group 4A Elements (3)
    • 19.9-11: The Group 5A Elements (3)
    • 19.12-13: The Group 6A Elements (4)
    • 19.14: Halogen Oxoacids and Oxoacid Salts [94-103[ (2)
    • 19: Chapter Problems (3)
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  • Chapter 20: Transition Elements and Coordination Chemistry
    • 20: Key Concept Problems (5)
    • 20.1-2: Electron Configurations and Properties of Transition Elements (3)
    • 20.3: Oxidation States (3)
    • 20.4: Chemistry of Selected Transition Elements (4)
    • 20.5-6: Coordination Compounds; Ligands (5)
    • 20.7: Naming Coordination Compounds (3)
    • 20.8-9: Isomers (2)
    • 20.10-12: Color of Complexes; Valence Bond and Crystqal Field Theories (2)
    • 20: Chapter Problems (2)
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  • Chapter 21: Metals and Solid-State Materials
    • 21: Key Concept Problems (7)
    • 21.1: Sources of the Metallic Elements (2)
    • 21.2: Metallurgy (6)
    • 21.3: Iron and Steel (1)
    • 21.4: Bonding in Metals (3)
    • 21.5-6: Semiconductors and Semicondcutor Applications (7)
    • 21.7: Superconductors
    • 21.8-9: Ceramics and Composites (5)
    • 21: Chapter Problems (6)
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  • Chapter 22: Nuclear Chemistry
    • 22: Key Concept Problems (2)
    • 22.1: Nuclear Reactions and Their Characteristics
    • 22.2: Nuclear Reactions and Radioactivity (6)
    • 22.3: Radioactive Decay Rates (9)
    • 22.4: Nuclear Stability
    • 22.5: Energy Changes during Nuclear Reactions (6)
    • 22.6: Nucler Fission and Fusion
    • 22.7: Nucler Transmutation (2)
    • 22.8: Detecting and Measuring Radioactivity
    • 22.9: Biological Effects of Radiation
    • 22.10: Applications of Nuclear Chemistry
    • 22: Chapter Problems (5)
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  • Chapter 23: Organic Chemistry
    • 23: Key Concept Problems (5)
    • 23.1: The Nature of Organic Molecules
    • 23.2, 8: Functional Groups and Isomers (8)
    • 23.2-6: Alkanes (12)
    • 23.7: Reactions of Alkanes
    • 23.8: Families of Organic Molecules: Functional Groups
    • 23.9-11: Alkenes, Alkynes, and Aromatic Compounds (20)
    • 23.12-14: Alcohols, Amines, and Carbonyl Compounds (15)
    • 23.15: Polymers (3)
    • 23: Chapter Problems (5)
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  • Chapter 24: Biochemistry
    • 24: Key Concept Problems (4)
    • 24.1: Biochemical Energy
    • 24.2-5: Amino Acids, Peptides, and Proteins (16)
    • 24.3: Molecular Handedness (6)
    • 24.4: Proteins
    • 24.5: Levels of Protein Structure
    • 24.6-9: Carbohydrates (5)
    • 24.10: Lipids (10)
    • 24.11-13: Nucleic Acids (8)
    • 24: Chapter Problems (6)
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Group Quantity Questions
Chapter 1: Chemistry: Matter and Measurement
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1.T 1 001
Chapter 2: Atoms, Molecules, and Ions
2.P 71 028 029 030 031 033 034 035 036 037 039 040 041 042 043 044 045 046 047 048 049 050 051 052 053 055 057 058 059 060 061 062 063 064 065 066 067 068 069 070 071 072 073 074 075 076 077 078 079 081 082 083 085 087 089 091 092 093 095 096 097 098 099 100 101 103 105 107 109 111 113 115
2.T 1 001
Chapter 3: Formulas, Equations and Moles
3.P 27 026 033 035 036 038 041 043 047 049 051 053 057 059 061 063 069 071 079 081 083 089 091 097 099 101 105 108
Chapter 4: Reactions in Aqueous Solution
4.P 21 016 023 024 026 028 031 033 035 043 055 059 063 069 071 073 081 083 084 085 086 091
Chapter 5: Periodicity and Atomic Structure
5.P 17 022 023 026 027 031 035 037 043 047 055 059 061 067 071 075 079 087
Chapter 6: Ionic Bonds and Some Main-Group Chemistry
6.P 11 028 031 033 037 039 045 047 059 061 065 089
Chapter 7: Covalent Bonds and Molecular Structure
7.P 37 035 039 041 047 048.mrv 050.mrv 051.mrv 052.mrv 053 053.mrv 055 058.mrv 059.mrv 060.mrv 061 062.mrv 063.mrv 064.mrv 065.mrv 067 071 073 075 087 088 091 097.mrv 098.mrv 099.mrv 100.mrv 101 104.mrv 107.mrv 109.mrv 110.mrv 111.mrv 123
7.T 2 001 002
Chapter 8: Thermochemistry: Chemical Energy
8.P 20 026 028 033 039 041 045 047 053 055 059 061 063 069 075 077 089 093 095 097 109
Chapter 9: Gases: Their Properties and Behavior
9.P 15 026 027 029 039 047 049 055 057 059 063 071 079 087 095 101
Chapter 10: Liquids, Solids, and Phase Changes
10.P 16 020 021 025 026 031 037 039 051 053 059 061 071 073 089 101 115
Chapter 11: Solutions and Their Properties
11.P 39 031 036 037 038 041 046 047 051 053 055 056 057 059 060 061 063 066 067 071 072 081 083 085 087 088 089 092 096 097 099 100 102 103 109 111 115 118 119 121
Chapter 12: Chemical Kinetics
12.P 42 015 022 024 026 027 029 033 035 039 043 047 049 050 051 053 054 055 056 057 059 062 063 068 071 074 077 078 079 084 085 086 091 094 095 096 103 104 106 108 111 115 116
Chapter 13: Chemical Equilibrium
13.P 40 029 031 033 040 041 043 048 049 052 056 057 059 061 063 064 065 067 070 071 072 075 077 079 082 083 085 086 087 089 093 095 096 098 099 103 107 119 120 123 129
Chapter 14: Aqueous Equilibria: Acids and Bases
14.P 32 018 031 034 035 037 040 044 045 047 049 051 052 053 055 057 061 063 064 071 075 081 086 087 089 091 092 093 097 098 103 112 119
Chapter 15: Applications of Aqueous Equilibria
15.P 29 034 037 038 040 043 045 053 055 057 059 061 067 069 071 077 079 081 083 089 091 093 097 099 101 107 111 121 127 133
Chapter 16: Thermodynamics: Entropy, Free Energy, and Equilibrium
16.P 47 024 025 031 033 034 038 041 042 045 046 047 050 053 058 059 060 061 064 067 068 069 070 072 073 075 076 077 079 084 085 089 090 091 093 094 095 099 101 104 107 113 115 117 119 120 123 125
Chapter 17: Electrochemistry
17.P 41 016 017 027 032 034 035 038 044 047 052 053 055 057 059 061 063 065 067 068 069 071 073 075 077 079 081 083 084 085 086 087 089 098 101 103 105 108 109 111 119 123
Chapter 18: Hydrogen, Oxygen, and Water
18.P 30 004 017 023 025 028 030 031 035 039 042 045 053 054 055 058 061 067 069 072 080 085 086 091 094 095 098 099 103 107 110
Chapter 19: The Main-Group Elements
19.P 32 016 018 022 023 024 025 027 028 029 031 033 035 036 039 043 047 051 053 056 061 068 075 080 083 085 090 093 096 102 107 113 116
Chapter 20: Transition Elements and Coordination Chemistry
20.P 29 008 016 023 026 027 033 035 040 046 047 051 057 060 064 067 069 071 073 075 079 081 082 085 091 095 104 107 114 123
Chapter 21: Metals and Solid-State Materials
21.P 37 001 003 008 013 014 018 021 026 028 031 034 038 039 040 041 045 052 058 063 067 074 078 079 080 081 082 088 092 095 099 102 113 114 115 122 123 130
Chapter 22: Nuclear Chemistry
22.P 30 021 023 024 029 032 033 035 041 048 049 050 051 052 053 054 055 057 062 063 065 066 072 073 074 079 081 084 085 087 090
Chapter 23: Organic Chemistry
23.P 68 030.mrv 031.mrv 032 035.mrv 037.mrv 038 040.mrv 041 041.mrv 042.mrv 043.mrv 044 045 047 048 049 052 053 054.mrv 055 055.mrv 057 059.mrv 060.mrv 061 062 063 064 065 066.mrv 067.mrv 069 069.mrv 070.mrv 071.mrv 072 073 074.mrv 075.mrv 076 077 078.mrv 079.mrv 080.mrv 081.mrv 082.mrv 083.mrv 084 085 086 087 088 092 095 096.mrv 097 097.mrv 098.mrv 099.mrv 100.mrv 103 106.mrv 107.mrv 110 110.mrv 111 113 114.mrv
Chapter 24: Biochemistry
24.P 55 025 027 029 031 032 033 035 035.mrv 036.mrv 037.mrv 038 038.mrv 040 041 043 044 045 048 048.mrv 049.mrv 050 051 053.mrv 054 054.mrv 055.mrv 057 058 060.mrv 061.mrv 062 066 067 068.mrv 069.mrv 070 071.mrv 073.mrv 074 074.mrv 075.mrv 076 077 079 080 081 084 087 089 091 094.mrv 095 096.mrv 097 099.mrv
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